Blue-black shiny surface that is initially
strongly bonded to the steel. Generally
associated with hot rolled steel sections like
angle iron and plate.
Possible Causes
Steel sections and plates are produced
by rolling steel while still red hot. The steel
reacts with oxygen in the air to form oxide
scales.
How Can I Fix This Problem
Mill scale is a reasonably inert material
in principle and might prove to be highly
protective coating if it adheres well.
However, it can be brittle and during
handling of steelwork, parts of the scale
tend to flake off with comparative ease.
Mill scale sets up a galvanic corrosion cell
when in contact with steel. Consequently
at breaks in the mill scale quite deep pitting
corrosion may occur and at the edges
rust creep will start which will appear
inconsistent and patchy as seen in the
photo above.
In most cases it is advisable to remove mill
scale prior to painting by means of abrasive
blast or acid pickling