Thin light white powdery deposit on
galvanized sheets. Generally seen on
unpainted galvanized sheets. Painting over
white rust can result in paint peeling. Not
to be confused with “Paint peeling from
galvanized substrates - Part 2
Possible Causes
Galvanized components which were
tightly stacked together with the presence of
moisture. Generally occurs during storage
and or transportation. The exclusion of
carbon dioxide and presence of moisture
in tightly stacked bundles can result in the
formation of unstable zinc hydroxide. Once
the galvanized surface is exposed to the
atmosphere with the presence of carbon
dioxide no further formation of soluble
zinc hydroxide will occur and a stable zinc
carbonate film will develop.
The moisture present can be from various
sources i.e. rolling fluids during profiling,
exposure to rain and dew, condensation
in stacked sheets due to rapid changes
in temperature and a lack of ventilation
between individual sheets even under
covered conditions. Drying buildings and
wet floors could also contribute to elevated
humidity levels
How Can I Fix This Problem
Asses the degree of the galvanized
coating’s depletion. Remove white rust at
spot areas with a stiff bristle brush (not a
wire brush). Check residual zinc coating
thickness with magnetic thickness gauge.
SANS 121 (SABS ISO 1461) makes
allowance for galvanized coating repairs
Superficial white rust that has not resulted
in severe zinc coating loss needs to be
removed prior to painting as any loose
deposits will impair paint adhesion. Small
areas can be removed by abrading with a
stiff bristle brush (not a wire brush). Large
areas can be treated with proprietary
products or simple chemical solutions.
i.e. 1% solution of Trisodium Phosphate
or 1% solution of Potassium or Sodium
Dichromate slightly acidified with Sulphuric
acid pH6. The solutions may leave a
stained surface. In all cases effected
sheets should be thoroughly washed
and dried after treatment. Follow the
appropriate precautions when working with
hazardous materials. Follow manufacturer’s
instructions.
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